Aerosol Formation In Gas-Phase Monoterpene Ozonolysis At Near-Atmospheric Concentration
Price
Free (open access)
Transaction
Volume
35
Pages
6
Published
1999
Size
491 kb
Paper DOI
10.2495/EURO991291
Copyright
WIT Press
Author(s)
Richard Winterhalter, Peter Neeb and Geert K. Moortgat
Abstract
Aerosol Formation in Gas-Phase Monoterpene Ozonolysis at Near-Atmospheric Concentration A contribution to subproject CMD Richard Winterhalter, Peter Neeb and Geert K. Moortgat Max-Planck-Institut fur Chemie, Division of Atmospheric Chemistry, P.O.Box 3060, D-55020Mainz, Germany Introduction Large amounts of terpenes are globally emitted (Zimmerman et al., 1978; Guenther et al, 1995) and the gas-to-particle conversion upon atmospheric degradation is suspected to form a main fraction of the secondary organic aerosol (SOA). Estimates range from 30 to 270 Tg y~* SOA compared to 140 Tg y~* anthropogenic and 90 Tg y~* biogenic sulfate (Andreae and Crutzen, 1997). For more accurate estimates, the understanding of the gas- phase mechanisms as well as the aerosol formation processes has to be improved. Results from smog chamber experiments (Hoffmann et al, 1997a) indicate, that the te
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