Alkyl(dimethyl)ethoxysilanes - Valuable Agents For The Hydrophobization Of Natural Stones
Price
Free (open access)
Transaction
Volume
42
Pages
10
Published
1999
Size
899 kb
Paper DOI
10.2495/STR990221
Copyright
WIT Press
Author(s)
J. Grobe & Chr. Zeine
Abstract
For the preservation and restoration of historic monuments, both hydrophobization of natural sandstones and consolidation (strengthening) of damaged structures are of comparable importance. In practice a separation of these applicational measures would be highly desirable, but unfortunately they often are interdependent. Thus, the conventional hydrophobic treatment of sandstones with alkyl-triethoxysilanes after hydrolysis and polycondensation of the monomers leads to a three-dimensional network with strong adhesion to the surface by covalent and adsorptive bonding resulting in a serious increase in firmness and reduced elasticity (enhanced E-modulus). Consequently the treated zone differs from the untreated area in its stress-strain behaviour with respect to thermal
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